Photoelectrochemical regeneration of all vanadium redox species for construction of a solar rechargeable flow cell
نویسندگان
چکیده
منابع مشابه
A Numerical Simulation of Vanadium Redox Flow Batteries
The recent penetration of renewable sources in the energy system caused a transformation of the needs of the distribution system and amplified the need of energy storage systems to properly balance the electricity grid. Among electrochemical energy storage devices, all vanadium flow batteries are those of the most promising technologies due to their high efficiency, long lifetime, reliability a...
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This paper examines vanadium chloride solutions as electrolytes for an all-vanadium redox flow battery. The chloride solutions were capable of dissolving more than 2.3 M vanadium at varied valence states and remained stable at 0-50 °C. The improved stability appeared due to the formation of a vanadium dinuclear [V(2)O(3)·4H(2)O](4+) or a dinuclear-chloro complex [V(2)O(3)Cl·3H(2)O](3+) in the s...
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The proton exchange membrane (PEM) fuel cell is a green energy producer which converts chemical energy to electricity in high yield. Alternatively, the vanadium redox flow battery (VRB) is one of the best rechargeable batteries because of its capability to average loads and output power sources. These two systems are modeled by Nernst equation and electrochemical rules. An effective energy gene...
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Solar rechargeable flow cells (SRFCs) provide an attractive approach for in situ capture and storage of intermittent solar energy via photoelectrochemical regeneration of discharged redox species for electricity generation. However, overall SFRC performance is restricted by inefficient photoelectrochemical reactions. Here we report an efficient SRFC based on a dual-silicon photoelectrochemical ...
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ژورنال
عنوان ژورنال: Journal of Energy Chemistry
سال: 2018
ISSN: 2095-4956
DOI: 10.1016/j.jechem.2017.04.005